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PVC丁基防水嵌縫膠的固化

  • 發布時間 : 2025-12-18 12:06:15
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(Summary description)Customized SILICONE STRUCTURAL SEALANT from China manufacturer refers to the adhesive with high strength, can bear large load, aging resistance, fatigue resistance and corrosion resistance, and has stable performance within the expected life. It is suitable for bearing the bonding of strong structural parts. Non structural adhesive has low strength and poor durability. It can only be used for bonding, sealing and fixing of ordinary and temporary properties, and cannot be used for structural adhesive bonding. NEUTRAL SILICONE WETHERPROOF SEALANT from China manufacturer is a structural adhesive with waterproof function. Silicone glue refers to the adhesive based on silicone rubber. According to different functions, it can be divided into structural adhesive, potting adhesive, sealant, thermal conductive adhesive, flame retardant adhesive and so on.

PVC丁基防水嵌縫膠的固化

(Summary description)Customized SILICONE STRUCTURAL SEALANT from China manufacturer refers to the adhesive with high strength, can bear large load, aging resistance, fatigue resistance and corrosion resistance, and has stable performance within the expected life. It is suitable for bearing the bonding of strong structural parts. Non structural adhesive has low strength and poor durability. It can only be used for bonding, sealing and fixing of ordinary and temporary properties, and cannot be used for structural adhesive bonding. NEUTRAL SILICONE WETHERPROOF SEALANT from China manufacturer is a structural adhesive with waterproof function. Silicone glue refers to the adhesive based on silicone rubber. According to different functions, it can be divided into structural adhesive, potting adhesive, sealant, thermal conductive adhesive, flame retardant adhesive and so on.

  • 發布時間 : 2025-12-18 12:06:15
  • Views:
Information

       將已制備好的PVC丁基防水嵌縫膠用刮板均勻涂在隔離紙上,長2030 cm、寬6一10 cm、厚0.2 cm。放入鼓風干燥箱高溫烘烤固化,固化時間為30 min,取出試片,裁剪備用。

測定或表征

       (1)-NCO值:采用二正丁胺滴定法測試聚氨醋樹脂中一NCO質量分數。稱取約1g左右樣品于干燥錐形瓶中,加入25 mL甲苯溶解樣品,準確加入25 mL二正丁胺一甲苯溶液,加塞密閉后充分振蕩,靜置15 min;隨后加入異丙醇100 mL和5滴嗅甲酚綠指示劑,用0.1 mol幾的HC1標準溶液滴定至終點(由藍至黃),同時作空白試驗。

       (2)力學性能:按照GB/T 528-2009標準,采用萬能拉力試驗機測定PVC試片的拉伸強度、斷裂伸長率;按照GB/T 529-2009標準,采用萬能拉力試驗機測定撕裂強度。

       (3)硬度:按照GB/T 531-1999標準,采用邵氏硬度計進行測定。

       (4)對鋁板的粘接力:將已制備好的PVC丁基防水嵌縫膠打膠條均勻地涂在鋁板上,參考QC/T 1024-2015標準中附件A的剝離粘接性測試方法,對丁基防水嵌縫膠進行粘接測試。

不同聚合度的PVC樹脂對耐高溫性能的影響

       為驗證不同聚合度的PVC樹脂對耐高溫性能的影響,我們選擇3種不同聚合度的PVC樹脂制備成丁基防水嵌縫膠,分別在140,170和200 ℃固化30 min,測試其力學性能并觀察外觀,測試結果如表所示。

       由表可知:低聚合度樹脂(PSL-31)在140 ℃固化能表現出較好的力學性能,但隨著固化溫度提高,顏色逐漸變黃轉黑,斷裂伸長率出現明顯下降,硬度增加,拉伸強度先增加后減少。表明200 ℃高溫導致低聚合度PVC分子鏈段斷裂,發生脫HC1反應,形成長共扼多烯結構,導致外觀發黃。相應地,中等聚合度樹脂(PSM-31)也出現類似規律,但耐溫性要好于PSL-31。高聚合度樹脂(PSH-10)隨著固化溫度升高,力學性能并未出現明顯下降,顏色輕微發黃,但在140 ℃固化時力學性能不及PSL-31o說明PVC聚合度越高,固化溫度越高,高溫固化的力學性能也越好,因此高溫固化的丁基防水嵌縫膠優先選用高聚合度的PVC樹脂。http://www.kzgjfl.cn/

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